Search results for " Low molecular weight gelator"

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Geminal Imidazolium Salts: A new Class of Gelators

2012

The gelling behavior of some geminal diimidazolium salts was investigated in solvents differing in polarity and hydrogen bond donor ability. The used salts, namely the 3,3'-di-n-decyl-1,1'(1,4-phenylenedimethylene)diimidazolium dibromide [p-Xyl-(decim)(2)][Br](2) (1), the 3,3'-di-n-dodecyl-1,1'(1,4-phenylenedimethylene)diimidazolium dibromide [p-Xyl-(dodecim)(2)][Br](2) (2), and the 3,3'-di-n-dodecyl-1,1'(1,4-phenylenedimethylene)diimidazolium ditetrafluoroborate [p-Xyl-(dodecim)(2)][BF(4)](2) (3), differ in the alkyl chain length and in the anion properties, such as size, shape, and coordination ability. In all cases in which gelation process was observed, the obtained gels were characteri…

Supramolecular chemistrychemistry.chemical_compoundBromidePolymer chemistryElectrochemistryMoleculeOrganic chemistryGeneral Materials ScienceSpectroscopyAlkylchemistry.chemical_classificationMolecular StructureGeminalHydrogen bondChemistryImidazolesHydrogen BondingSurfaces and InterfacesSettore CHIM/06 - Chimica OrganicaCondensed Matter PhysicsResonance (chemistry)Geminal imidazolium salts Low molecular weight gelator OrganogelThermodynamicsSaltsChemical stabilityGelsOrganogels Hydrogels imidazolium salts
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